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Total Synthesis of Diltiazem. en The JuliColonna Epoxidation has been applied to the Total Synthesis of Diltiazem From Adger Barkley Bergeron Cappi Flowerdew Jackson McCague Nugent Roberts Improved procedure for JuliaColonna asymmetric epoxidation of unsaturated ketones total synthesis of diltiazem and Taxol TM sidechain Chem Soc